自动化流动注射停流动力学分析仪的研制及其性能测试

本文研制了一套自动化流动注射停流动力学分析仪，该仪器由苹果Ⅱ型微机通过１２位ＡＤ／ＤＡ卡，流动注射停流控制仪及用ＢＡＳＩＣ语言编制的软件控制泵的起动和停止，试样的输送和混合，数据采集和处理，结果显示和打印，通过以铁（Ⅲ）与硫氰酸盐的反应体系采用固定时间法和以钒（Ｖ）的胶束催化反庆体系采用安始速法的现场测试证明，该仪器具有结构简单，操作方便，恒温性能好，通用性强等特点。     

全氟辛基磺酸酸度函数H0的测定

It is reported in this paper that the acidity function H_0 of perfluorooctanesulfonic acid (POSA) is -12.11±0.03, which was measured first time by ~1H NMR method, in term of the α-H chemical shifts of the acid-ether systems, using 98% to 100% H_2SO_4 as reference standards. This method provides a new procedure for measuring the H_0 value of solid perfluoroalkanesulfonie acid C_nH_(2n+1)SO_3H(n>7).     

Facile cyclic ammonium salt with the smallest size for high performance electric double layer capacitors

A novel cyclic ammonium salt, N,N-dimethylpyrrolidinium tetrafluoroborate (P₁₁-BF₄), was successfully synthesized for the first time. The smallest cyclic structure of P₁₁-BF₄ induced high solubility and conductivity in PC, which can easier enter the micropores of activated carbon and occupy more surface area during charge/discharge process.     

Tree-gel and loop-gel conversions in nonlinear polymerization

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混合价聚十五钒酸盐[V_(15)O_(36)Cl](NH_4)_3Na_7·30H_2O的合成与晶体结构

以XRD法确定制得的标题晶体属空间群D_(3A)~3,a=13.111,c=11.130。结构由帕特逊-极小函数法结合差值法解出,经精修得一致性因子R_w=0.0344。晶胞中坐落在6m2特殊位置上的是包合1个Cl~-的聚十五钒酸根[V_(15)O_(36)Cl]~(10-),配合键价法确认这是四价钒占主导地位的一类特种混合价同多酸根。     

铈杂多配离子-水滑石超分子层柱材料ZnAl-Ce(PMoV)2的插层组装、表征及催化性能

以十四酸根阴离子柱撑Zn-Al水滑石Zn0.77Al0.22(OH)2.0.22C13H27COO.0.81 H2O(记为ZnAl-14A)为预撑前体,在水溶液中用离子交换法将以2∶17缺位杂多酸根离子(P2Mo16VO61)11-记为(P Mo V)为配体的稀土杂多配阴离子Ce(P2Mo16VO61)219-(记为Ce(PMoV)2)插层组装到水滑石层板间,合成了一种具有大的层间距(3.37 nm)的超分子插层材料Zn0.77Al0.23(OH)2.0.0105[Ce(P1.9Mo15.7V1.1O61)2].0.011C13H27COO.0.83H2O(记为ZnAl-Ce(PMoV)2)。用ICP,IR,XRD和DTA对产物的组成和结构进行了表征。结果表明,该产物中Ce(PMoV)2配阴离子沿其长轴垂直于层板的方向分布于水滑石层间;产物具有规整的层状结构和热稳定性;产物对乙酸与正丁醇的酯化反应,二甘醇的脱水-环化反应和H2O2氧化环己烷的反应有良好的催化性能,且易于回收重复使用。     

Synthesis and photoluminescence properties of 8-hydroxyquinoline derivatives and their metallic complexes

Three new 8-hydroxyquinoline derivatives, i.e. 5-[(4-styryl-benzylidene)-amino]-quinolin-8-ol (1), 5-[(4-bromo-2-fluoro-benzylidene)-amino]-quinoline-8-ol (2) and 2-[2-(9-ethyl-9H-carbazol-2yl)-vinyl]-quinolin-8-ol (3), and their metallic complexes were synthesized and identified by ultraviolet-visible (UV-Vis), ¹H nuclear magnetic resonance (¹H NMR), Fourier transform infrared spectrometer (FTIR), mass spectrometry (MS) spectra and elemental analyses. Their fluorescence properties were studied by photoluminescence, which indicated that the luminescence wavelength of 5-and 2-substitued-8-hydroxyquinoline derivatives shifted to red in comparison with that of 8-hydroxyquinoline. Meanwhile, the fluorescence lifetime of 2-[2-(9-ethyl-9H-carbazol-2yl)-vinyl]-quinolin-8-ol and its zinc complex showed long lifetime in benzene solution. __________ Translated from Chinese Journal of Organic Chemistry, 2007, 27(3): 402–408 [译自: 有机化学]     

含有脲桥结构的苯氧乙酰胺衍生物的合成与表征

为了开发新型高效低毒杀菌剂,设计合成了5个未见文献报道的含有脲桥结构的苯氧乙酰胺类化合物,其结构经元素分析,1H NMR和IR确证.     

偏氟乙烯的聚合反应

本文研究了用有机引发剂引发偏氟乙烯的水相聚合,并对制得的聚偏氟乙烯的性质进行了研究。有机引发剂引发聚合的聚偏氟乙烯的热稳定性、强度、结晶度和熔点均比用过硫酸盐引发聚合的聚偏氟乙烯高。     

磁疗手术胆结石的红外光谱观测

本文报道用Nicolet 170 SXFT-IR红外光谱仪观测磁疗手术胆结石、磁疗破碎排出胆结石及服中草药破碎胆结石的红外光谱,分析并比较了它们的光谱特征。